By Thomas A. Unger
The target of this instruction manual is to explain the elemental synthesis route(s) for the manufacture of 687 insecticides. vital additional info comprises the 5 appendices:
I. typical Names: The regular identify Appendix shows the chemical functionality of the compound. If the compound has a couple of functionality, all services are indicated. thus, the synthesis direction of the compound is located less than the 1st functionality indicated during this Appendix.
II. exchange Names: whilst basically the alternate identify of the product is understood, the corresponding prevalent identify is located during this Appendix.
III. uncooked fabrics and Intermediates: This Appendix lists all insecticides, the synthesis of which makes use of a given uncooked fabric or intermediate.
IV. Synthesis of uncooked fabrics and Inter-mediates: The synthesis routes of uncooked fabrics and Intermediates are offered during this Appendix.
V. Chemical services: This Appendix lists all items that have an analogous chemical functionality. The systhesis route(s) for every product are defined less than the heading of the most functionality. whilst a product has extra then one major chemical functionality, it's indexed less than all its functions.
An abbreviated Contents is indexed less than; the quantity in ( ) point out the variety of insecticides in that type, whose synthesis is defined.
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Extra resources for Pesticide Synthesis Handbook
6 dimethyl aniline - I mC I C-I methoxy acetaldehyde 1t2 0 cl- "~/c-~ ' C"- ' C~ 0--- I --. -@, 0=- l C . -I N-- C--- "" I , // I \ Cl-- c-- c dimethachlor O C-I Cl chloro acetyl chloride Pretilachlor Uses: herbicide, Trade names : Type: rice Rifit (Ciba) ami d e Synthesis : As d i m e t h a c h l o r I I I I i/,o -- c-- c-- c-- o-- c-- c I I l I \ with propoxy acetaldehyde I Cl--c--c I N and -c-c-~c-c_ I I I . 6 diethyl anil ine I , ~ - - N"1 , , , i i I c - - c - - o - - i ~ " c--c-- , > pretilachlor ' ' I i 21 22 Pesticides Synthesis Handbook alternate route : \/ I N I I ~ I I i C--C--O--C--C-- I --C-- N I ' f I o =ffiS ~ - o I 0 I -C-I --C-.
6 diethyl anil ine I , ~ - - N"1 , , , i i I c - - c - - o - - i ~ " c--c-- , > pretilachlor ' ' I i 21 22 Pesticides Synthesis Handbook alternate route : \/ I N I I ~ I I i C--C--O--C--C-- I --C-- N I ' f I o =ffiS ~ - o I 0 I -C-I --C-. I 0 i # Cl--c--c I \ I I - - C =- --C"- I O Cl i I p. toluene sulfonic acid 2 propoxy ethyl ester pretilachlor Propisochlor Uses: herbicide, maize, sunflowers, soyabeans, potatoes Trade names: Type: Proponit (Nitrokemia) amide Synthesis: I --C-- As dimethaehlor with ---C----C----O----C I I O \ isopropyoxy formaldehyde \/ N and --c--c--f/"x ) - - c - 2 methyl 6 ethyl aniline O II CI-- cI --c l j \ ll~ N C I --C-- i I o--c--et I -, propisochlor I I C-- Amides and Similar Functions Diphenamid Uses: herbicide, cotton, soyabeans, potatoes, fruit, ornamentals, vegetables, tobacco Dymid (Lilly), Enide (Up John) names : Trade Type: amide Synthesis : XC~.
I Cl \ N ~' C - - Cram C - - ' ' ~ - cffi c I d ia I ly I amine dichlormid I I 17 18 Pesticides Synthesis Handbook Diethatyl-Ethyl Uses: herbicide, Trade names : Type: potatoes, Antor red beet, soyabeans, sugarbeet, wheat (NorAm) amide Synthesis: o ! \ , C--C-- t I o + el- ! 6 dimethyl aniline - I mC I C-I methoxy acetaldehyde 1t2 0 cl- "~/c-~ ' C"- ' C~ 0--- I --. -@, 0=- l C . -I N-- C--- "" I , // I \ Cl-- c-- c dimethachlor O C-I Cl chloro acetyl chloride Pretilachlor Uses: herbicide, Trade names : Type: rice Rifit (Ciba) ami d e Synthesis : As d i m e t h a c h l o r I I I I i/,o -- c-- c-- c-- o-- c-- c I I l I \ with propoxy acetaldehyde I Cl--c--c I N and -c-c-~c-c_ I I I .