Oxidations in Organic Chemistry Reductions in Organic by Milo%s Hudlický

By Milo%s Hudlický

An entire resource of knowledge on oxidations of natural compounds, with emphasis on preparative facets and effects. vital positive factors comprise: discussions on oxidizing brokers and on oxidation reactions utilizing them; correlation tables exhibiting what oxidizing brokers are compatible for conversions of specific compounds to their oxidation items; and a suite of usual laboratory techniques for the most forms of oxidations. All details is supported by way of examples, thorough referencing, and indexing.

Show description

Read or Download Oxidations in Organic Chemistry Reductions in Organic Chemistry: Volume 1: Oxidations in Organic Chemistry (Acs Monograph) PDF

Similar organic books

Chemistry of Heterocyclic Compounds: Pyridazines, Volume 28

Content material: bankruptcy I actual homes of Pyridazines (pages 1–22): Anne G. Lenhert and Raymond N. CastleChapter II The Pyridazinones, Alkoxy? and Aryloxy? Pyridazines, and comparable Compounds (pages 23–218): James W. Mason and Duane L. AldousChapter III Halopyridazines (pages 219–352): Duane L. Aldous and Raymond N.

Handbook of Heterocyclic Chemistry

This re-creation is designed to supply a one-volume total photograph of the topic of heterocyclic chemistry

Annual Reports in Organic Synthesis–1975

Annual experiences in natural Synthesis – 1975 is a suite of worthy information regarding the developments within the box of natural chemistry. stated info is gifted within the kind of photos and/or natural chemistry equations. The publication covers subject matters similar to carbon-carbon bond forming reactions; oxidations; discount rates; synthesis of heterocycles; man made arrangements; and different miscellaneous reactions.

Synthetic Applications of 1,3-Dipolar Cycloaddition Chemistry Toward Heterocycles and Natural Products

Focusing totally on the literature that has seemed when you consider that 1984, Padwa (chemistry, Emory U. ) and Pearson (chemistry, U. of Michigan) current 12 contributions that survey purposes of [3+2]-cycloadditions in natural synthesis. The chapters conceal nitrones, nitronates, azomethine ylides, carbonyl ylides, thiocarbonyl ylides, nitrile oxides, nitrile ylides and nitrile imines, diazoalkanes, azides, mesoionic ring platforms, impression of exterior reagents, and uneven reactions

Additional info for Oxidations in Organic Chemistry Reductions in Organic Chemistry: Volume 1: Oxidations in Organic Chemistry (Acs Monograph)

Sample text

7 0 , 372 (1958). (64d) Leuna-Werke, H. Schade and M . Thiel, German Patent 1063602 (1957). (64e) Leuna-Werke, F. Asinger, M . Thiel, and H . Hauthal, German Patent 1068171 (1957). (65) O. Rohm, German Patent 262707 (1912). (66) H. Reinhardt and J. Szurrat, Gummi u. Asbest 1 0 ( 8 ) , 422-466 (1957). (67) L. Haitinger, Monatsh. Chem. 4 , 165 (1883); S. Onufrowicz, Ber. deut. chem Ges. 2 3 , 3355 (1890); M . Lange, ibid. 2 1 , 260 (1888); Gesellschaft Chim. Ind, Basel, German Patent 379003 (1921); Swiss priority (1920); Farbenfabriken Bayer A G , German Patent 400242 (1920); German Patent 409783 (1921); C.

C-SH1 II II s s 8 hrs • boiling X — > O'' ^ N-C-CH,-C-N^ I s I s J R = C H , - C H t - C H 8- ^0 N - / The susceptibility to attack displayed by the vinyl group is also illus­ trated by the conversion of vinylpyrrolidone into N-thioacetylpyrrolidone (111b) (Example 31a). I 1 ^ Lo + S N CH=CH, 8 hrs 165° > I I l J=o N S=C CH8 Acetylene in the presence of secondary amines readily undergoes a double attack by sulfur in the absence of water to give dithiooxalamides (113) (Example 32). No other data appear to exist regarding the degra­ dation by sulfur on both sides.

22) J. A. King and F. H . McMillan, J. Am. Chem. Soc. 68, 632 (1946). (23) D. B. Pattison and M . Carmack, J. Am. Chem. Soc. 68, 2033 (1946). (24) R. T. Gerry and E. V. Brown, J. Am. Chem. Soc. 75, 740 (1953). (25) D. Nightingale and R. A. Carpenter, / . Am. Chem. Soc. 71, 3560 (1949). (26) C. Willgerodt and F. H . Merk, J. prakt. Chem. 80, 192 (1909). (27) Cf. also R. T. Arnold, E. Schultz, and H . Klug, / . Am. Chem. Soc. 66, 1606 (1944). (28) J. A. King and F. H. McMillan, J. Am. Chem. Soc.

Download PDF sample

Rated 4.31 of 5 – based on 27 votes