Modern Reduction Methods by Pher G. Andersson, Ian J. Munslow

By Pher G. Andersson, Ian J. Munslow

With its entire evaluate of contemporary relief equipment, this booklet positive aspects prime quality contributions permitting readers to discover trustworthy options speedy and simply. The monograph treats the relief of carbonyles, alkenes, imines and alkynes, in addition to reductive aminations and go and heck couplings, ahead of completing off with sections on kinetic resolutions and hydrogenolysis.An vital lab significant other for each chemist.

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These differences in selectivity are probably due to the steric and electronic properties of the biaryl backbone of these ligands [93b]. The hydrogenation of β-substituted itaconic acids and derivatives is more difficult. 19). 4 Reduction of itaconic acids. Substrate Catalyst H2 (bar) ee % Configuration Ref. 20 with Rh-Me-Duphos in which a trisubstituted olefin is reduced to afford a chiral succinate [94]. 1 Mechanistic Aspects of the Ru-(BINAP)-Catalyzed Hydrogenation of Carboxylic Acids Several groups, most notably those of Noyori [95], Halpern et al.

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Roberts, S. and Whittall, J. 33 34 1 Reduction of Functionalized Alkenes 21 22 23 24 25 26 27 28 29 (2006) Journal of the American Chemical Society, 128, 3922. S. J. (2005) Organometallics, 24, 4824. A. L. (1993) Journal of the American Chemical Society, 115, 10125. G. G. (1998) Journal of the American Chemical Society, 120, 657. J. (2000) Accounts of Chemical Research, 33, 363. F. P. (1995) Journal of the American Chemical Society, 117, 9375. , Schmid, R. and Obrech, D. (1994) Helvetica Chimica Acta, 77, 1395.

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