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I,. Goodman, and B. R. Baker, J. Am. Chem. , 81, 898 (1959). 4. Baxter, J. , and A. S. Perlin, Can. J. , S8,2217 (1960). 5 . Bishop, C. , F. Blank, and P. E. Gardner, Can. J. , 38,869 (1960). 6. Bishop, C. , and F. P. Cooper, Can. J. , 38,388 (1960). 7. Bishop, C. , and F. P. Cooper, Can. J. , SS, 793 (1960). 8. Bishop, C. , and F. P. Cooper, unpublished results. 9. , in (12), p. 169. 10. , E. L. Hirst, L. Hough, J. K. N. Jones, and W. H. Wadman, Nature, 161, 720 (1948). 11. , G. Herrstrom, G.
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This conclusion was supported by the subsequent isolation of oligosac- 32 C. T. BISHOP 4 11. A p i r z o n Temp. /min. A E J Fig. 13. Separation of methanolysia products from methylated mannan (5) ,(A) Methyl 2,3,4,6tetra-O-methyl a-D-mannopyranoside. (B) Unknown. (C) Methyl 3,4,6-tri-O-methyl a-D-mannopyranoside. (D) Methyl 2,3,6-tri-Omethyl a-D-mannopyranoside. (E) Methyl 3,4di-O-methyl a-D-mannopyranoside. charides containing both D-xylose and D-glucose from an enzymic hydrolyzate of the same glucomannan (34).