Amino, Nitrosco and Nitro Compounds and Their Derivatives:

Chapter 1 Structural chemistry (pages 1–51): S. Sorriso
Chapter 2 Stereochemistry and conformations (pages 53–83): Morton Raban and Jeremy Greenblatt
Chapter three The chemistry of ionized amino, nitroso and nitro compounds within the gasoline part (pages 85–126): Helmut Schwarz and Karsten Levsen
Chapter four Rearrangements concerning nitroso and nitro compounds (pages 127–153): D. L. H. Williams
Chapter five The spectroscopy, photophysics and photochemistry of saturated amines (pages 155–180): Arthur M. Halpern
Chapter 6 Photochemistry of nitro and nitroso compounds (pages 181–290): Yuan L. Chow
Chapter 7 Radiation chemistry of amines, nitro and nitroso compounds (pages 291–318): Clive L. Greenstock
Chapter eight Electrochemistry of nitro compounds (pages 319–337): Albert J. Fry
Chapter nine Electrochemistry of amines (pages 339–359): Wayne E. Britton
Chapter 10 Radical anion reactions of nitro compounds (pages 361–393): Nathan Kornblum
Chapter eleven Direct aminations (pages 395–416): Tuvia Sheradsky
Chapter 12 Pyrolysis of nitrites, nitrates, nitro compounds, nitroso compounds and amines (pages 417–458): Leslie Batt
Chapter thirteen Nitrones and nitronic acid derivatives: their constitution and their roles in synthesis (pages 459–564): Eli Breuer
Chapter 14 Nitroxides (pages 565–622): Hans Gunter Aurich
Chapter 15 Enamines and ynamines (pages 623–714): G. Pitacco and E. Valentin

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Extra resources for Amino, Nitrosco and Nitro Compounds and Their Derivatives: Volume 1 (1982)

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J. Donohue and K. N. , 9, 960 (1956). 79. K. N. Trueblood, E. Goldish and J. , 14, 1009 (1961). 80. H. H. Cady and A. C. , 18. 485 (1965). 81. J. R. , 22, 545 (1967). 82. J. R. Holden, C. Dickinson and C . M. Bock, J. Phys. , 76, 3597 (1972). 83. C. Dickinson and J. M. , 21, 663 (1966). 84. A. T. McPhail and G. A. Sim, J. Chem. ,227 (1965). 8 5 . D. C. Hughes and J. Trotter, J. Chern. SOC. ( A ) , 2181 (1971). 86. J. H. , 21, 473 (1966). 87. J. Trotter, S. H. Whitlow and T. Zobel, J. Chem. SOC.

020 A) and very probably of the same order as the difference one would expect to observe between aliphatic and aromatic nitro compounds. e. 482(20) respectively]. 478(6) ofio ~- N-0' ~ C-N TABLE 12. 5 5 10 10 28 8 13 3 dC “Bond lengths in 8, and angles in degrees. ”Average. ‘Angle between the planes of the nitro and phenyl groups. “Corrected. The uncorrected values are very close to the corrected ones. “There are two crystallographically independent molecules in the asymmetric unit. There are no significant differences in bond lengths and angles between the two molecules.

The microwave spectrum of 2-aminopyridine in gaslo4 consists of pairs of lines of comparable intensity, rather than a single series of decreasing intensity. This fact may be interpreted in terms of the presence of low-lying vibrational states. From the conformational point of view this is in agreement with the presence of an inversion mode for the -NH2 group, as found for aniline and aliphatic amines (again in the gas phase). 998 A, the angle 4 the same side. 6". This value is sensibly smaller than that found in aniline (39")67, in agreement with the fact that in aminopyridine there is a greater contribution from quinonoid forms than in aniline.

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