Advances in Physical Organic Chemistry by J.P. Richard (Eds.)

By J.P. Richard (Eds.)

Advances in actual natural Chemistry offers the chemical group with authoritative and significant exams of the numerous features of actual natural chemistry. the sphere is a speedily constructing one, with effects and methodologies discovering software from biology to reliable country physics. * stories the appliance of quantitative and mathematical tools in the direction of figuring out chemical difficulties * Multidisciplinary volumes hide natural, organometallic, bioorganic, enzymes and fabrics subject matters

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136. 137. 138. 139. 140. 141. 142. 143. 144. 145. 146. 147. 148. J. BUURMA Lebedeva N, Ranganathan R, Bales BL. J Phys Chem B 2007;111:5781–93. Lebedeva N, Bales BL. J Phys Chem B 2006;110:9791–9. Ranganathan R, Vautier-Giongo C, Bales BL. J Phys Chem B 2003;107:10312–8. Abuin E, Lissi E. J Colloid Interface Sci 1986;112:178. Yoshino A, Yoshida T, Okabayashi H, Kamaya H, Ueda I. J Colloid Interface Sci 1998;198:319–22. Menger FM. Acc Chem Res 1979;12:111–7. Mukerjee P, Cardinal JR, Desai NR. In: Mittal KL, editor.

197 Nevertheless, comparison of the rates of hydrolysis of 4-nitrophenyl chloroformate 1a and 4-nitrophenyl 2,2-dichloropropionate 2 shows a COLLOIDAL MEDIUM EFFECTS ON ORGANIC REACTIONS 25 marked difference in the rate effects exerted by different surfactants. Whereas the hydrolysis of 4-nitrophenyl chloroformate 1a was accelerated by cationic micelles and most strongly decelerated by anionic micelles, the micellar rate constants for hydrolysis of 4-nitrophenyl 2,2-dichloropropionate 2 were far more similar.

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